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Beilstein J. Org. Chem. 2016, 12, 50–72, doi:10.3762/bjoc.12.7
Graphical Abstract
Figure 1: Structures of α-, β- and γ-CD. Individual carbon atom numbering is shown for one D-glucopyranose su...
Figure 2: Associations of hydrophobic substituents (circled) (a) and their disruption through host–guest comp...
Figure 3: Decrease of aqueous solution viscosity at a shear rate of 50 s−1 due to α-CD (circles), β-CD (recta...
Figure 4: The effect of (a) α-CD, (b) β-CD and (c) γ-CD on the hydrophobic interactions between n-C18H37 subs...
Figure 5: The effect of SDS addition on viscosity shear rate dependence for 2 wt % aqueous PAAodn solutions c...
Figure 6: Host–guest complexation between polymers with cyclodextrin and hydrophobic substituents.
Figure 7: Variation of viscosity with mole ratio of CD substituents to hydrophobic substituents on poly(acryl...
Figure 8: Illustration of the competitive intermolecular host–guest complexation of either the adamantyl subs...
Figure 9: Competitive host–guest complexations in which either the adamantyl substituent (red) or the n-hexyl...
Figure 10: (a) Substituted chitosan in which acyl- and adamantyl-substitution is 5% and 12 %, respectively. (b...
Figure 11: The formation of a AD-PEG micelle followed by the formation of a AD-PEG/α-CD supramolecular hydroge...
Figure 12: Interaction of PEG-b-PAA block copolymer with cis-diamminedichloroplatinum(II), cisplatin, to form ...
Figure 13: Solution to hydrogel transitions (a)–(d) for a PAAddn segment in the presence of competitive photo-...
Figure 14: Structures of the poly(acrylate)-based polymers PAAAzo (trans), PAAAzo (cis), PAA3α-CD and PAA6α-CD...
Figure 15: Variation of viscosity of a PAA6α-CD/PAAAzo solution (circles) and a PAA3α-CD/PAAAzo solution (tria...
Figure 16: The structures proposed for the poly(ethylene glycol)-b-poly(ethylamine)-g-dextran·γ-CD, PEG-PEI-de...
Figure 17: Structure of poly(ethylene glycol) polyrotaxane with adamantyl end substituents, and its temperatur...
Figure 18: Copolymers of either (a) N,N-dimethylacrylamide (DMAA) or (b) N-isopropylacrylamine (NIPAAM) with 1...
Figure 19: The copolymer of isopropylacrylamine and methacrylated β-CD (a) and its complexation of the anions ...
Figure 20: Solution to hydrogel transitions for two segments of PAAddn in the presence of β-CD and change in t...
Figure 21: Preparation of a β-CD and adamantyl substituted acrylamide polymer hydrogel involving host–guest co...
Figure 22: Aqueous solutions of the polymers poly-β-CD and poly-α-BrNP form the poly-β-CD/poly-α-BrNP hydrogel ...
Figure 23: (a) Randomly β-CD substituted poly(acrylate), PAA-6β-CD. (b) Randomly ferrocenyl substituted poly(a...
Figure 24: (a) The β-CD, adamantyl and ferrocenyl substituted pAAm and pNiPAAM polymers. (b) The β-CD, adamant...